Heavily Graphitic-Nitrogen Self-doped High-porosity Carbon for the Electrocatalysis of Oxygen Reduction Reaction

نویسندگان

  • Tong Feng
  • Wenli Liao
  • Zhongbin Li
  • Lingtao Sun
  • Dongping Shi
  • Chaozhong Guo
  • Yu Huang
  • Yi Wang
  • Jing Cheng
  • Yanrong Li
  • Qizhi Diao
چکیده

Large-scale production of active and stable porous carbon catalysts for oxygen reduction reaction (ORR) from protein-rich biomass became a hot topic in fuel cell technology. Here, we report a facile strategy for synthesis of nitrogen-doped porous nanocarbons by means of a simple two-step pyrolysis process combined with the activation of zinc chloride and acid-treatment process, in which kidney bean via low-temperature carbonization was preferentially adopted as the only carbon-nitrogen sources. The results show that this carbon material exhibits excellent ORR electrocatalytic activity, and higher durability and methanol-tolerant property compared to the state-of-the-art Pt/C catalyst for the ORR, which can be mainly attributed to high graphitic-nitrogen content, high specific surface area, and porous characteristics. Our results can encourage the synthesis of high-performance carbon-based ORR electrocatalysts derived from widely-existed natural biomass.

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عنوان ژورنال:

دوره 12  شماره 

صفحات  -

تاریخ انتشار 2017